Di-μ-chlorido-bis[chloridobis(dimethyl sulfoxide)dioxidouranium(VI)]
نویسندگان
چکیده
In the crystal structure of the title compound, [U(2)Cl(4)O(4)(C(2)H(6)OS)(4)], the compound has a centrosymmetric dimeric structure bridged by two chloride anions. Each U(VI) atom is seven-coordinate in a penta-gonal-bipyramidal geometry. In the equatorial plane of the uranyl unit there are two O atoms from non-adjacent dimethyl sulfoxides and three chloride ions (of which two chlorides are bridging). The compound is of inter-est as an anhydrous starting material of the uran-yl(VI) ion.
منابع مشابه
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2007